Trigun

In a lawless, barren world, Vash the Stampede, a rugged outlaw with a 60 billion double dollar bounty on his head, roams from town to town, leaving destruction in his wake. Despite his notorious reputation, Vash is a pacifist at heart, incapable of harming a fly. Meryl and Milly, two insurance agents, are tasked with keeping him under surveillance to prevent further damage. As they get to know Vash, they begin to question whether he's truly the ruthless criminal they've been told he is. But there's more to Vash's past than meets the eye, and his stumbling, bumbling nature may be more than just a cover.

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Some TV shows that have similar genres and were produced around the same time as Trigun include WondLa, The Legend of Korra, Star Wars Rebels, Star Wars: Visions, Invincible, Fullmetal Alchemist: Brotherhood.